Platinum-Promoted Ga/Al2O3 as Highly Active, Selective, and Stable Catalyst for the Dehydrogenation of Propane**

نویسندگان

  • Jesper J H B Sattler
  • Ines D Gonzalez-Jimenez
  • Lin Luo
  • Brien A Stears
  • Andrzej Malek
  • David G Barton
  • Beata A Kilos
  • Mark P Kaminsky
  • Tiny W G M Verhoeven
  • Eline J Koers
  • Marc Baldus
  • Bert M Weckhuysen
چکیده

A novel catalyst material for the selective dehydrogenation of propane is presented. The catalyst consists of 1000 ppm Pt, 3 wt% Ga, and 0.25 wt% K supported on alumina. We observed a synergy between Ga and Pt, resulting in a highly active and stable catalyst. Additionally, we propose a bifunctional active phase, in which coordinately unsaturated Ga(3+) species are the active species and where Pt functions as a promoter.

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عنوان ژورنال:

دوره 53  شماره 

صفحات  -

تاریخ انتشار 2014